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(2S,3S)-3-(3-Bromo­phen­yl)-6,6-dimethyl-2-nitro-2,3,6,7-tetra­hydro­benzo­furan-4(5H)-one

The title compound, C(16)H(16)BrNO(4), has two adjacent chiral C atoms and both have an S configuration. The fused cyclo­hex-2-enone and di­hydro­furan rings both adopt envelope conformations, with the quaternary C atom and the nitro-substituted C atoms as the respective flap. The flap atoms lie 0.6...

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Detalles Bibliográficos
Autores principales: Wang, Yifeng, Yao, Minjie, Dong, Kun, Xu, Danqian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793765/
https://www.ncbi.nlm.nih.gov/pubmed/24109352
http://dx.doi.org/10.1107/S160053681301920X
Descripción
Sumario:The title compound, C(16)H(16)BrNO(4), has two adjacent chiral C atoms and both have an S configuration. The fused cyclo­hex-2-enone and di­hydro­furan rings both adopt envelope conformations, with the quaternary C atom and the nitro-substituted C atoms as the respective flap. The flap atoms lie 0.607 (3) and −0.253 (2) Å, respectively, from the mean plane of the remaining ring atoms on opposite sides. The dihedral angle between the mean plane of the four coplanar atoms of the di­hydro­furan ring and the phenyl ring is 86.16 (3)°. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming a ladder motif parallel to the b axis.