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(2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one
In the molecule of the title compound, C(24)H(19)ClN(2)O, the terminal quinolinyl residues are close to perpendicular to each other [dihedral angle 83.72 (4)°]. The quinolinyl residues are connected by and inclined to the prop-2-en-1-one bridge, with the C(ar)—C(ar)—C—C (ar = aromatic) torsion angl...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793770/ https://www.ncbi.nlm.nih.gov/pubmed/24109357 http://dx.doi.org/10.1107/S1600536813019405 |
| _version_ | 1782287112551268352 |
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| author | Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Prasath, R. |
| collection | PubMed |
| description | In the molecule of the title compound, C(24)H(19)ClN(2)O, the terminal quinolinyl residues are close to perpendicular to each other [dihedral angle 83.72 (4)°]. The quinolinyl residues are connected by and inclined to the prop-2-en-1-one bridge, with the C(ar)—C(ar)—C—C (ar = aromatic) torsion angles being 71.01 (17) and 20.6 (2)°. The crystal structure features phenyl–carbonyl C—H⋯O interactions and π–π interactions between centrosymmetrically related quinolinyl residues [3.5341 (10) and 3.8719 (9) Å], which together lead to a three-dimensional architecture. |
| format | Online Article Text |
| id | pubmed-3793770 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37937702013-10-09 (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(24)H(19)ClN(2)O, the terminal quinolinyl residues are close to perpendicular to each other [dihedral angle 83.72 (4)°]. The quinolinyl residues are connected by and inclined to the prop-2-en-1-one bridge, with the C(ar)—C(ar)—C—C (ar = aromatic) torsion angles being 71.01 (17) and 20.6 (2)°. The crystal structure features phenyl–carbonyl C—H⋯O interactions and π–π interactions between centrosymmetrically related quinolinyl residues [3.5341 (10) and 3.8719 (9) Å], which together lead to a three-dimensional architecture. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793770/ /pubmed/24109357 http://dx.doi.org/10.1107/S1600536813019405 Text en © Prasath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title | (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_full | (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_fullStr | (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_full_unstemmed | (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_short | (2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| title_sort | (2e)-3-(2-chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793770/ https://www.ncbi.nlm.nih.gov/pubmed/24109357 http://dx.doi.org/10.1107/S1600536813019405 |
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