2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione

The title compound, C(28)H(40)N(2)O(2)S(2), was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionyl­thiol­actam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipse...

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Detalles Bibliográficos
Autores principales: Walker, Ashley, Forsyth, Craig M., Perlmutter, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793777/
https://www.ncbi.nlm.nih.gov/pubmed/24109364
http://dx.doi.org/10.1107/S1600536813019211
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author Walker, Ashley
Forsyth, Craig M.
Perlmutter, Patrick
author_facet Walker, Ashley
Forsyth, Craig M.
Perlmutter, Patrick
author_sort Walker, Ashley
collection PubMed
description The title compound, C(28)H(40)N(2)O(2)S(2), was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionyl­thiol­actam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C—C bond with a C—C—C—C— torsion angle of 20.4 (3)°.
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spelling pubmed-37937772013-10-09 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione Walker, Ashley Forsyth, Craig M. Perlmutter, Patrick Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(40)N(2)O(2)S(2), was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionyl­thiol­actam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C—C bond with a C—C—C—C— torsion angle of 20.4 (3)°. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793777/ /pubmed/24109364 http://dx.doi.org/10.1107/S1600536813019211 Text en © Walker et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Walker, Ashley
Forsyth, Craig M.
Perlmutter, Patrick
2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title_full 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title_fullStr 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title_full_unstemmed 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title_short 2-(10′,10′-Dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
title_sort 2-(10′,10′-dimethyl-3′-sulfanyl­idene-4′-aza­tri­cyclo­[5.2.1.0(1,5)]decan-2′­-yl)-10,10-dimethyl-4-aza­tri­cyclo­[5.2.1.0(1,5)]decane-3-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793777/
https://www.ncbi.nlm.nih.gov/pubmed/24109364
http://dx.doi.org/10.1107/S1600536813019211
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