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(2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)

The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butyl­nitrone starting material. The attached carbonyl groups are not coplanar with the neighboring di­hydro­isoxazole ring and the phen...

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Detalles Bibliográficos
Autores principales: Sandhya, R., Sithambaresan, M., Prathapan, S., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793779/
https://www.ncbi.nlm.nih.gov/pubmed/24109366
http://dx.doi.org/10.1107/S1600536813019508
Descripción
Sumario:The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butyl­nitrone starting material. The attached carbonyl groups are not coplanar with the neighboring di­hydro­isoxazole ring and the phenyl rings they are bonded to, with torsion angles of 59.26 (8), 17.53 (11), 16.52 (12) and 52.86 (7)°. The dihedral angle between the di­hydro­isoxazole ring and the directly attached phenyl group is 86.86 (8)°. There are two nonclassical inter­molecular C—H⋯O hydrogen-bonding inter­actions that operate together with an inter­molecular C—H⋯π inter­action to form a supramolecular architecture in the crystal system.