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(2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone)
The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butylnitrone starting material. The attached carbonyl groups are not coplanar with the neighboring dihydroisoxazole ring and the phen...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793779/ https://www.ncbi.nlm.nih.gov/pubmed/24109366 http://dx.doi.org/10.1107/S1600536813019508 |
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author | Sandhya, R. Sithambaresan, M. Prathapan, S. Kurup, M. R. Prathapachandra |
author_facet | Sandhya, R. Sithambaresan, M. Prathapan, S. Kurup, M. R. Prathapachandra |
author_sort | Sandhya, R. |
collection | PubMed |
description | The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butylnitrone starting material. The attached carbonyl groups are not coplanar with the neighboring dihydroisoxazole ring and the phenyl rings they are bonded to, with torsion angles of 59.26 (8), 17.53 (11), 16.52 (12) and 52.86 (7)°. The dihedral angle between the dihydroisoxazole ring and the directly attached phenyl group is 86.86 (8)°. There are two nonclassical intermolecular C—H⋯O hydrogen-bonding interactions that operate together with an intermolecular C—H⋯π interaction to form a supramolecular architecture in the crystal system. |
format | Online Article Text |
id | pubmed-3793779 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937792013-10-09 (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) Sandhya, R. Sithambaresan, M. Prathapan, S. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butylnitrone starting material. The attached carbonyl groups are not coplanar with the neighboring dihydroisoxazole ring and the phenyl rings they are bonded to, with torsion angles of 59.26 (8), 17.53 (11), 16.52 (12) and 52.86 (7)°. The dihedral angle between the dihydroisoxazole ring and the directly attached phenyl group is 86.86 (8)°. There are two nonclassical intermolecular C—H⋯O hydrogen-bonding interactions that operate together with an intermolecular C—H⋯π interaction to form a supramolecular architecture in the crystal system. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793779/ /pubmed/24109366 http://dx.doi.org/10.1107/S1600536813019508 Text en © Sandhya et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sandhya, R. Sithambaresan, M. Prathapan, S. Kurup, M. R. Prathapachandra (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title | (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title_full | (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title_fullStr | (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title_full_unstemmed | (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title_short | (2-tert-Butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
title_sort | (2-tert-butyl-3-phenyl-2,3-dihydroisoxazole-4,5-diyl)bis(phenylmethanone) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793779/ https://www.ncbi.nlm.nih.gov/pubmed/24109366 http://dx.doi.org/10.1107/S1600536813019508 |
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