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(2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)

The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butyl­nitrone starting material. The attached carbonyl groups are not coplanar with the neighboring di­hydro­isoxazole ring and the phen...

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Autores principales: Sandhya, R., Sithambaresan, M., Prathapan, S., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793779/
https://www.ncbi.nlm.nih.gov/pubmed/24109366
http://dx.doi.org/10.1107/S1600536813019508
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author Sandhya, R.
Sithambaresan, M.
Prathapan, S.
Kurup, M. R. Prathapachandra
author_facet Sandhya, R.
Sithambaresan, M.
Prathapan, S.
Kurup, M. R. Prathapachandra
author_sort Sandhya, R.
collection PubMed
description The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butyl­nitrone starting material. The attached carbonyl groups are not coplanar with the neighboring di­hydro­isoxazole ring and the phenyl rings they are bonded to, with torsion angles of 59.26 (8), 17.53 (11), 16.52 (12) and 52.86 (7)°. The dihedral angle between the di­hydro­isoxazole ring and the directly attached phenyl group is 86.86 (8)°. There are two nonclassical inter­molecular C—H⋯O hydrogen-bonding inter­actions that operate together with an inter­molecular C—H⋯π inter­action to form a supramolecular architecture in the crystal system.
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spelling pubmed-37937792013-10-09 (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone) Sandhya, R. Sithambaresan, M. Prathapan, S. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The phenyl and tert-butyl groups of the title compound, C(27)H(25)NO(3), exhibit a trans configuration in agreement with the stereochemistry of the Z phenyl-N-tert-butyl­nitrone starting material. The attached carbonyl groups are not coplanar with the neighboring di­hydro­isoxazole ring and the phenyl rings they are bonded to, with torsion angles of 59.26 (8), 17.53 (11), 16.52 (12) and 52.86 (7)°. The dihedral angle between the di­hydro­isoxazole ring and the directly attached phenyl group is 86.86 (8)°. There are two nonclassical inter­molecular C—H⋯O hydrogen-bonding inter­actions that operate together with an inter­molecular C—H⋯π inter­action to form a supramolecular architecture in the crystal system. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793779/ /pubmed/24109366 http://dx.doi.org/10.1107/S1600536813019508 Text en © Sandhya et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sandhya, R.
Sithambaresan, M.
Prathapan, S.
Kurup, M. R. Prathapachandra
(2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title_full (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title_fullStr (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title_full_unstemmed (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title_short (2-tert-Butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
title_sort (2-tert-butyl-3-phenyl-2,3-di­hydro­isoxazole-4,5-di­yl)bis­(phenyl­methanone)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793779/
https://www.ncbi.nlm.nih.gov/pubmed/24109366
http://dx.doi.org/10.1107/S1600536813019508
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AT kurupmrprathapachandra 2tertbutyl3phenyl23dihydroisoxazole45diylbisphenylmethanone