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1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole
In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetracyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The trifluoromethylphenyl ring is roughly coplanar with the phenanthr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793785/ https://www.ncbi.nlm.nih.gov/pubmed/24109372 http://dx.doi.org/10.1107/S1600536813019351 |
Sumario: | In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetracyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The trifluoromethylphenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetracyclic system [dihedral angle = 11.02 (6)°], while the methoxyphenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intramolecular C—H ⋯π interactions involving the methoxyphenyl ring and the central phenanthroline ring, as well as an intermolecular C—H⋯π interaction involving the phenanthroline ring. In addition, there is an intermolecular π–π interaction involving the central phenanthroline ring and the trifluoromethylphenyl ring [centroid–centroid distance = 3.685 (2) Å], as well as C—H⋯N interactions linking the molecules into dimers. |
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