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1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole
In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetracyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The trifluoromethylphenyl ring is roughly coplanar with the phenanthr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793785/ https://www.ncbi.nlm.nih.gov/pubmed/24109372 http://dx.doi.org/10.1107/S1600536813019351 |
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author | Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathi, A. Sakthivel, P. |
author_facet | Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathi, A. Sakthivel, P. |
author_sort | Mohandas, T. |
collection | PubMed |
description | In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetracyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The trifluoromethylphenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetracyclic system [dihedral angle = 11.02 (6)°], while the methoxyphenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intramolecular C—H ⋯π interactions involving the methoxyphenyl ring and the central phenanthroline ring, as well as an intermolecular C—H⋯π interaction involving the phenanthroline ring. In addition, there is an intermolecular π–π interaction involving the central phenanthroline ring and the trifluoromethylphenyl ring [centroid–centroid distance = 3.685 (2) Å], as well as C—H⋯N interactions linking the molecules into dimers. |
format | Online Article Text |
id | pubmed-3793785 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937852013-10-09 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathi, A. Sakthivel, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetracyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The trifluoromethylphenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetracyclic system [dihedral angle = 11.02 (6)°], while the methoxyphenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intramolecular C—H ⋯π interactions involving the methoxyphenyl ring and the central phenanthroline ring, as well as an intermolecular C—H⋯π interaction involving the phenanthroline ring. In addition, there is an intermolecular π–π interaction involving the central phenanthroline ring and the trifluoromethylphenyl ring [centroid–centroid distance = 3.685 (2) Å], as well as C—H⋯N interactions linking the molecules into dimers. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793785/ /pubmed/24109372 http://dx.doi.org/10.1107/S1600536813019351 Text en © Mohandas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathi, A. Sakthivel, P. 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title | 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title_full | 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title_fullStr | 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title_full_unstemmed | 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title_short | 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole |
title_sort | 1-(4-methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1h-phenanthro[9,10-d]imidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793785/ https://www.ncbi.nlm.nih.gov/pubmed/24109372 http://dx.doi.org/10.1107/S1600536813019351 |
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