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1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole

In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetra­cyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The tri­fluoro­methyl­phenyl ring is roughly coplanar with the phenanthr...

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Autores principales: Mohandas, T., Sathishkumar, R., Jayabharathi, J., Pasupathi, A., Sakthivel, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793785/
https://www.ncbi.nlm.nih.gov/pubmed/24109372
http://dx.doi.org/10.1107/S1600536813019351
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author Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathi, A.
Sakthivel, P.
author_facet Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathi, A.
Sakthivel, P.
author_sort Mohandas, T.
collection PubMed
description In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetra­cyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The tri­fluoro­methyl­phenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetra­cyclic system [dihedral angle = 11.02 (6)°], while the meth­oxy­phenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intra­molecular C—H ⋯π inter­actions involving the meth­oxy­phenyl ring and the central phenanthroline ring, as well as an inter­molecular C—H⋯π inter­action involving the phenanthroline ring. In addition, there is an inter­molecular π–π inter­action involving the central phenanthroline ring and the tri­fluoro­methyl­phenyl ring [centroid–centroid distance = 3.685 (2) Å], as well as C—H⋯N inter­actions linking the mol­ecules into dimers.
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spelling pubmed-37937852013-10-09 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathi, A. Sakthivel, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(19)F(3)N(2)O, a phenanthroline-fused imidazole tetra­cyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The tri­fluoro­methyl­phenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetra­cyclic system [dihedral angle = 11.02 (6)°], while the meth­oxy­phenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intra­molecular C—H ⋯π inter­actions involving the meth­oxy­phenyl ring and the central phenanthroline ring, as well as an inter­molecular C—H⋯π inter­action involving the phenanthroline ring. In addition, there is an inter­molecular π–π inter­action involving the central phenanthroline ring and the tri­fluoro­methyl­phenyl ring [centroid–centroid distance = 3.685 (2) Å], as well as C—H⋯N inter­actions linking the mol­ecules into dimers. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793785/ /pubmed/24109372 http://dx.doi.org/10.1107/S1600536813019351 Text en © Mohandas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathi, A.
Sakthivel, P.
1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title_full 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title_fullStr 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title_full_unstemmed 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title_short 1-(4-Meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1H-phenanthro[9,10-d]imidazole
title_sort 1-(4-meth­oxy­phen­yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-1h-phenanthro[9,10-d]imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793785/
https://www.ncbi.nlm.nih.gov/pubmed/24109372
http://dx.doi.org/10.1107/S1600536813019351
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