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2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol
The asymmetric unit in the title compound, C(24)H(26)N(2)O(3), comprises two independent molecules (A and B). In molecule A, the central 2-hydroxyphenyl ring is inclined to the mean plane of the major component of the imidazolidine ring by 84.52 (14)°, and by 68.08 (9) and 47.48 (9)° to the outer p...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793786/ https://www.ncbi.nlm.nih.gov/pubmed/24109373 http://dx.doi.org/10.1107/S1600536813019417 |
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author | Rivera, Augusto Cárdenas, Lorena Ríos-Motta, Jaime Kučeráková, Monika Dušek, Michal |
author_facet | Rivera, Augusto Cárdenas, Lorena Ríos-Motta, Jaime Kučeráková, Monika Dušek, Michal |
author_sort | Rivera, Augusto |
collection | PubMed |
description | The asymmetric unit in the title compound, C(24)H(26)N(2)O(3), comprises two independent molecules (A and B). In molecule A, the central 2-hydroxyphenyl ring is inclined to the mean plane of the major component of the imidazolidine ring by 84.52 (14)°, and by 68.08 (9) and 47.48 (9)° to the outer phenol rings. The later are inclined to one another by 66.76 (9)° and by 78.12 (14) and 80.20 (14)° to the imidazoline ring mean plane. In molecule B, the central 2-hydroxyphenyl ring is inclined to the mean plane of the imidazolidine ring by 73.64 (10)°, and by 75.60 (8) and 38.32 (9)° to the outer phenol rings. The later are inclined to one another by 69.47 (9)° and by 82.60 (10) and 64.26 (10)° to the imidazolidine ring mean plane. In each of the independent molecules, two intramolecular O—H⋯N hydrogen bond form S(6) ring motifs. In disordered molecule A, the O—H groups of the 2-hydroxybenzyl groups are also involved in intramolecular O—H⋯O hydrogen bonds, with the O atom of the hydroxyphenyl group acting as the acceptor. In the crystal, A molecules are linked by pairs of O—H⋯O hydrogen bonds forming inversion dimers. These dimers are linked to the B molecules via O—H⋯O hydrogen bonds forming double-layered slabs lying parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3793786 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937862013-10-09 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol Rivera, Augusto Cárdenas, Lorena Ríos-Motta, Jaime Kučeráková, Monika Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit in the title compound, C(24)H(26)N(2)O(3), comprises two independent molecules (A and B). In molecule A, the central 2-hydroxyphenyl ring is inclined to the mean plane of the major component of the imidazolidine ring by 84.52 (14)°, and by 68.08 (9) and 47.48 (9)° to the outer phenol rings. The later are inclined to one another by 66.76 (9)° and by 78.12 (14) and 80.20 (14)° to the imidazoline ring mean plane. In molecule B, the central 2-hydroxyphenyl ring is inclined to the mean plane of the imidazolidine ring by 73.64 (10)°, and by 75.60 (8) and 38.32 (9)° to the outer phenol rings. The later are inclined to one another by 69.47 (9)° and by 82.60 (10) and 64.26 (10)° to the imidazolidine ring mean plane. In each of the independent molecules, two intramolecular O—H⋯N hydrogen bond form S(6) ring motifs. In disordered molecule A, the O—H groups of the 2-hydroxybenzyl groups are also involved in intramolecular O—H⋯O hydrogen bonds, with the O atom of the hydroxyphenyl group acting as the acceptor. In the crystal, A molecules are linked by pairs of O—H⋯O hydrogen bonds forming inversion dimers. These dimers are linked to the B molecules via O—H⋯O hydrogen bonds forming double-layered slabs lying parallel to the bc plane. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793786/ /pubmed/24109373 http://dx.doi.org/10.1107/S1600536813019417 Text en © Rivera et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rivera, Augusto Cárdenas, Lorena Ríos-Motta, Jaime Kučeráková, Monika Dušek, Michal 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title | 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title_full | 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title_fullStr | 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title_full_unstemmed | 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title_short | 2,2′-{[2-(2-Hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
title_sort | 2,2′-{[2-(2-hydroxyphenyl)-4-methylimidazolidine-1,3-diyl]bis(methylene)}diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793786/ https://www.ncbi.nlm.nih.gov/pubmed/24109373 http://dx.doi.org/10.1107/S1600536813019417 |
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