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3-[1-(2-Hydroxyanilino)ethylidene]-3H-chromen-2,4-dione
The title compound is a new aminocoumarin derivative, C(17)H(13)NO(4), and was synthesized by the condensation of 2-aminophenol and 3-acetyl-4-hydroxycoumarin. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, the molecules are linked into chains extending in t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793787/ https://www.ncbi.nlm.nih.gov/pubmed/24109374 http://dx.doi.org/10.1107/S160053681301934X |
Sumario: | The title compound is a new aminocoumarin derivative, C(17)H(13)NO(4), and was synthesized by the condensation of 2-aminophenol and 3-acetyl-4-hydroxycoumarin. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, the molecules are linked into chains extending in the [010] direction by O—H⋯O hydrogen bonds. There is also a π–π stacking interaction between the bicyclic coumarin fragment and the phenol ring [centroid–centroid distance = 3.7510 (14) Å], and these ring systems form between them a dihedral angle of 53.3 (2)°. Intermolecular hydrogen bond C—H⋯O hydrogen bonding is also observed in the interconnection of the crystal packing. |
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