3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan

In the title compound, C(17)H(15)BrO(2)S, both the benzo­furan and 2-bromo­phenyl rings are virtually planar, with r.m.s. deviations of 0.009 (2) and 0.006 (2) Å, respectively. The dihedral angle between these mean planes is 89.31 (7)°. In the crystal, mol­ecules are linked via pairs of C—H⋯π inter­...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793790/
https://www.ncbi.nlm.nih.gov/pubmed/24109377
http://dx.doi.org/10.1107/S1600536813019867
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(17)H(15)BrO(2)S, both the benzo­furan and 2-bromo­phenyl rings are virtually planar, with r.m.s. deviations of 0.009 (2) and 0.006 (2) Å, respectively. The dihedral angle between these mean planes is 89.31 (7)°. In the crystal, mol­ecules are linked via pairs of C—H⋯π inter­actions into inversion dimers. These dimers are further linked by C—H⋯π inter­actions into supra­molecular chains running along the b axis. In addition, C—S⋯π inter­actions, with an S-to-ring-centroid distance of 3.50 (2) Å, are observed between inversion-related dimers.
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spelling pubmed-37937902013-10-09 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)BrO(2)S, both the benzo­furan and 2-bromo­phenyl rings are virtually planar, with r.m.s. deviations of 0.009 (2) and 0.006 (2) Å, respectively. The dihedral angle between these mean planes is 89.31 (7)°. In the crystal, mol­ecules are linked via pairs of C—H⋯π inter­actions into inversion dimers. These dimers are further linked by C—H⋯π inter­actions into supra­molecular chains running along the b axis. In addition, C—S⋯π inter­actions, with an S-to-ring-centroid distance of 3.50 (2) Å, are observed between inversion-related dimers. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793790/ /pubmed/24109377 http://dx.doi.org/10.1107/S1600536813019867 Text en © Choi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title_full 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title_fullStr 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title_full_unstemmed 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title_short 3-(2-Bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
title_sort 3-(2-bromo­phenyl­sulfin­yl)-2,5,7-trimethyl-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793790/
https://www.ncbi.nlm.nih.gov/pubmed/24109377
http://dx.doi.org/10.1107/S1600536813019867
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