1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol

The title compound, C(17)H(21)NO(2), was synthesized by the reaction of (1R)-(+)-3-benzyl­camphor and hydroxyl­amine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered...

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Autores principales: Boualy, Brahim, Harrad, Mohamed Anouar, Oudahmane, Abdelghani, Benharref, Ahmed, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793801/
https://www.ncbi.nlm.nih.gov/pubmed/24109388
http://dx.doi.org/10.1107/S160053681302000X
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author Boualy, Brahim
Harrad, Mohamed Anouar
Oudahmane, Abdelghani
Benharref, Ahmed
Berraho, Moha
author_facet Boualy, Brahim
Harrad, Mohamed Anouar
Oudahmane, Abdelghani
Benharref, Ahmed
Berraho, Moha
author_sort Boualy, Brahim
collection PubMed
description The title compound, C(17)H(21)NO(2), was synthesized by the reaction of (1R)-(+)-3-benzyl­camphor and hydroxyl­amine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered rings of the norboryl group displays a flattened envelope conformation, with the C atom carrying the methyl groups representing the flap for both rings. In the crystal, mol­ecules are linked into zigzag chains propagating along the b axis by O—H⋯N hydrogen bonds.
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spelling pubmed-37938012013-10-09 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol Boualy, Brahim Harrad, Mohamed Anouar Oudahmane, Abdelghani Benharref, Ahmed Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(21)NO(2), was synthesized by the reaction of (1R)-(+)-3-benzyl­camphor and hydroxyl­amine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered rings of the norboryl group displays a flattened envelope conformation, with the C atom carrying the methyl groups representing the flap for both rings. In the crystal, mol­ecules are linked into zigzag chains propagating along the b axis by O—H⋯N hydrogen bonds. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793801/ /pubmed/24109388 http://dx.doi.org/10.1107/S160053681302000X Text en © Boualy et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boualy, Brahim
Harrad, Mohamed Anouar
Oudahmane, Abdelghani
Benharref, Ahmed
Berraho, Moha
1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title_full 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title_fullStr 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title_full_unstemmed 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title_short 1,10,10-Trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
title_sort 1,10,10-trimethyl-5-phenyl-3-oxa-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-4-en-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793801/
https://www.ncbi.nlm.nih.gov/pubmed/24109388
http://dx.doi.org/10.1107/S160053681302000X
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