2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide

In the title compound, C(11)H(15)N(3)O(2)S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, i...

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Detalles Bibliográficos
Autores principales: Anderson, Brian J., Freedman, Michael B., Millikan, Sean P., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793802/
https://www.ncbi.nlm.nih.gov/pubmed/24109389
http://dx.doi.org/10.1107/S1600536813019831
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author Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
author_facet Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
author_sort Anderson, Brian J.
collection PubMed
description In the title compound, C(11)H(15)N(3)O(2)S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, inversion dimers linked by C—H⋯O inter­actions occur. Further C—H⋯O contacts link dimers into (010) chains.
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spelling pubmed-37938022013-10-09 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide Anderson, Brian J. Freedman, Michael B. Millikan, Sean P. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(15)N(3)O(2)S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, inversion dimers linked by C—H⋯O inter­actions occur. Further C—H⋯O contacts link dimers into (010) chains. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793802/ /pubmed/24109389 http://dx.doi.org/10.1107/S1600536813019831 Text en © Anderson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_full 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_fullStr 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_full_unstemmed 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_short 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_sort 2-[1-(2-hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-n-methyl­hydrazinecarbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793802/
https://www.ncbi.nlm.nih.gov/pubmed/24109389
http://dx.doi.org/10.1107/S1600536813019831
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