(2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate

In the title solvate, C(29)H(21)ClN(2)O(2)·C(3)H(6)O, a prop-2-en-1-one bridge links two quinolinyl residues; the latter are almost perpendicular [dihedral angle = 78.27 (6)°]. The dihedral angle between the quinonyl ring system and its pendant phenyl group is 59.78 (8)°. A small twist in the bridgi...

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Autores principales: Prasath, R., Sarveswari, S., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793806/
https://www.ncbi.nlm.nih.gov/pubmed/24109393
http://dx.doi.org/10.1107/S1600536813020217
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author Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Prasath, R.
collection PubMed
description In the title solvate, C(29)H(21)ClN(2)O(2)·C(3)H(6)O, a prop-2-en-1-one bridge links two quinolinyl residues; the latter are almost perpendicular [dihedral angle = 78.27 (6)°]. The dihedral angle between the quinonyl ring system and its pendant phenyl group is 59.78 (8)°. A small twist in the bridging prop-2-en-1-one group is noted [O=C—C=C torsion angle = −10.6 (3)°]. In the crystal, a three-dimensional architecture arises as a result of C—H⋯O and π–π stacking [centroid–centroid distances = 3.5504 (12)–3.6623 (12) Å].
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spelling pubmed-37938062013-10-09 (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate Prasath, R. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvate, C(29)H(21)ClN(2)O(2)·C(3)H(6)O, a prop-2-en-1-one bridge links two quinolinyl residues; the latter are almost perpendicular [dihedral angle = 78.27 (6)°]. The dihedral angle between the quinonyl ring system and its pendant phenyl group is 59.78 (8)°. A small twist in the bridging prop-2-en-1-one group is noted [O=C—C=C torsion angle = −10.6 (3)°]. In the crystal, a three-dimensional architecture arises as a result of C—H⋯O and π–π stacking [centroid–centroid distances = 3.5504 (12)–3.6623 (12) Å]. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793806/ /pubmed/24109393 http://dx.doi.org/10.1107/S1600536813020217 Text en © Prasath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasath, R.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
(2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title_full (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title_fullStr (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title_full_unstemmed (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title_short (2E)-3-(6-Chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
title_sort (2e)-3-(6-chloro-2-meth­oxy­quinolin-3-yl)-1-(2-methyl-4-phenyl­quinolin-3-yl)prop-2-en-1-one acetone monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793806/
https://www.ncbi.nlm.nih.gov/pubmed/24109393
http://dx.doi.org/10.1107/S1600536813020217
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AT ngseikweng 2e36chloro2methoxyquinolin3yl12methyl4phenylquinolin3ylprop2en1oneacetonemonosolvate
AT tiekinkedwardrt 2e36chloro2methoxyquinolin3yl12methyl4phenylquinolin3ylprop2en1oneacetonemonosolvate

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