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N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide

The mol­ecule of the title compound, C(42)H(32)N(6)O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenyl­benzohydrazide group. The pyrazole ring assumes an envelope conformation,...

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Autores principales: Ramli, Youssef, Karrouchi, Khalid, Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793807/
https://www.ncbi.nlm.nih.gov/pubmed/24109394
http://dx.doi.org/10.1107/S1600536813020035
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author Ramli, Youssef
Karrouchi, Khalid
Essassi, El Mokhtar
El Ammari, Lahcen
author_facet Ramli, Youssef
Karrouchi, Khalid
Essassi, El Mokhtar
El Ammari, Lahcen
author_sort Ramli, Youssef
collection PubMed
description The mol­ecule of the title compound, C(42)H(32)N(6)O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenyl­benzohydrazide group. The pyrazole ring assumes an envelope conformation, the C atom attached to the quinoxalin-3-yl ring system being the flap atom. The dihedral angle between the two phenyl rings of the phenyl­benzohydrazide group is of 58.27 (9)°. The mean plane through the pyrazole ring is nearly perpendicular to the quinoxaline ring system and to the phenyl ring attached to the opposite side, forming dihedral angles of 82.58 (7) and 87.29 (9)°, respectively. An intra­molecular C—H⋯O hydrogen bond is present. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds, forming inversion dimers, which are further connected by C—H⋯N hydrogen bonds into chains parallel to the b axis.
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spelling pubmed-37938072013-10-09 N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide Ramli, Youssef Karrouchi, Khalid Essassi, El Mokhtar El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(42)H(32)N(6)O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenyl­benzohydrazide group. The pyrazole ring assumes an envelope conformation, the C atom attached to the quinoxalin-3-yl ring system being the flap atom. The dihedral angle between the two phenyl rings of the phenyl­benzohydrazide group is of 58.27 (9)°. The mean plane through the pyrazole ring is nearly perpendicular to the quinoxaline ring system and to the phenyl ring attached to the opposite side, forming dihedral angles of 82.58 (7) and 87.29 (9)°, respectively. An intra­molecular C—H⋯O hydrogen bond is present. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds, forming inversion dimers, which are further connected by C—H⋯N hydrogen bonds into chains parallel to the b axis. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793807/ /pubmed/24109394 http://dx.doi.org/10.1107/S1600536813020035 Text en © Ramli et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramli, Youssef
Karrouchi, Khalid
Essassi, El Mokhtar
El Ammari, Lahcen
N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title_full N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title_fullStr N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title_full_unstemmed N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title_short N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-di­hydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
title_sort n′-phenyl-n′-[3-(2,4,5-triphenyl-2,5-di­hydro-1h-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793807/
https://www.ncbi.nlm.nih.gov/pubmed/24109394
http://dx.doi.org/10.1107/S1600536813020035
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