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2-[4-(2-Chloro­acet­yl)phen­yl]-2-methyl-1-(pyrrolidin-1-yl)propan-1-one

The asymmetric unit of the title compound, C(16)H(20)ClNO(2), contains two mol­ecules in which the dihedral angles between the benzene ring and the plane of the amide unit are 77.4 (1) and 81.1 (1)°. In both mol­ecules, the five-membered ring adopts an envelope conformation with one of the β-C atoms...

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Detalles Bibliográficos
Autor principal: Ren, Dong-mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793811/
https://www.ncbi.nlm.nih.gov/pubmed/24109398
http://dx.doi.org/10.1107/S1600536813020175
Descripción
Sumario:The asymmetric unit of the title compound, C(16)H(20)ClNO(2), contains two mol­ecules in which the dihedral angles between the benzene ring and the plane of the amide unit are 77.4 (1) and 81.1 (1)°. In both mol­ecules, the five-membered ring adopts an envelope conformation with one of the β-C atoms as the flap. In the crystal, mol­ecules are connected via C—H⋯O hydrogen bonds, forming chains along the b-axis direction. These chains are further linked by C—H⋯π inter­actions, forming a three-dimensional network.