1-Benzoyl-4-thio­biuret

In the title compound (systematic name: {[(phenyl­formamido)­carbon­yl]amino}­methane­thio­amide), C(9)H(9)N(3)O(2)S, both benzoyl and terminal thio­urea fragments adopt transoid conformations with respect to the central carbonyl O atom. The benzoyl and thio­biuret groups are almost coplanar, making...

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Detalles Bibliográficos
Autor principal: Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793812/
https://www.ncbi.nlm.nih.gov/pubmed/24109399
http://dx.doi.org/10.1107/S1600536813019983
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author Kang, Sung Kwon
author_facet Kang, Sung Kwon
author_sort Kang, Sung Kwon
collection PubMed
description In the title compound (systematic name: {[(phenyl­formamido)­carbon­yl]amino}­methane­thio­amide), C(9)H(9)N(3)O(2)S, both benzoyl and terminal thio­urea fragments adopt transoid conformations with respect to the central carbonyl O atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 4.40 (8)°. The mol­ecular structure is stabilized by two intra­molecular N—H⋯O hydrogen bonds. In the crystal, N—H⋯O and N—H⋯S hydrogen bonds link the mol­ecules into a tape running along [101].
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spelling pubmed-37938122013-10-09 1-Benzoyl-4-thio­biuret Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (systematic name: {[(phenyl­formamido)­carbon­yl]amino}­methane­thio­amide), C(9)H(9)N(3)O(2)S, both benzoyl and terminal thio­urea fragments adopt transoid conformations with respect to the central carbonyl O atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 4.40 (8)°. The mol­ecular structure is stabilized by two intra­molecular N—H⋯O hydrogen bonds. In the crystal, N—H⋯O and N—H⋯S hydrogen bonds link the mol­ecules into a tape running along [101]. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793812/ /pubmed/24109399 http://dx.doi.org/10.1107/S1600536813019983 Text en © Sung Kwon Kang 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kang, Sung Kwon
1-Benzoyl-4-thio­biuret
title 1-Benzoyl-4-thio­biuret
title_full 1-Benzoyl-4-thio­biuret
title_fullStr 1-Benzoyl-4-thio­biuret
title_full_unstemmed 1-Benzoyl-4-thio­biuret
title_short 1-Benzoyl-4-thio­biuret
title_sort 1-benzoyl-4-thio­biuret
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793812/
https://www.ncbi.nlm.nih.gov/pubmed/24109399
http://dx.doi.org/10.1107/S1600536813019983
work_keys_str_mv AT kangsungkwon 1benzoyl4thiobiuret

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