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1-(5-Bromo-2-oxoindolin-3-yl­idene)-4-phenyl­thio­semicarbazide

In the title compound, C(15)H(11)BrN(4)OS, the least-squares plane through the 5-bromo­isatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The mol­ecular conformation features intra­molecular N—H⋯N and N—H⋯O hydrogen bonds. In the crystal, mol­ecules are connected via pairs o...

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Detalles Bibliográficos
Autores principales: Bandeira, Katlen C. T., Bresolin, Leandro, Näther, Christian, Jess, Inke, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793820/
https://www.ncbi.nlm.nih.gov/pubmed/24109407
http://dx.doi.org/10.1107/S1600536813020497
Descripción
Sumario:In the title compound, C(15)H(11)BrN(4)OS, the least-squares plane through the 5-bromo­isatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The mol­ecular conformation features intra­molecular N—H⋯N and N—H⋯O hydrogen bonds. In the crystal, mol­ecules are connected via pairs of N—H⋯O inter­actions into centrosymmetric dimers. Additionally, π–π stacking inter­actions link mol­ecules into chains parallel to the a axis with short C⋯C distances being observed between the phenyl and thio­carbonyl [3.236 (8) Å] groups and between the thio­carbonyl and carbonyl [3.351 (4) Å] groups of stacked mol­ecules.