Cargando…
1-(5-Bromo-2-oxoindolin-3-ylidene)-4-phenylthiosemicarbazide
In the title compound, C(15)H(11)BrN(4)OS, the least-squares plane through the 5-bromoisatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The molecular conformation features intramolecular N—H⋯N and N—H⋯O hydrogen bonds. In the crystal, molecules are connected via pairs o...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793820/ https://www.ncbi.nlm.nih.gov/pubmed/24109407 http://dx.doi.org/10.1107/S1600536813020497 |
Sumario: | In the title compound, C(15)H(11)BrN(4)OS, the least-squares plane through the 5-bromoisatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The molecular conformation features intramolecular N—H⋯N and N—H⋯O hydrogen bonds. In the crystal, molecules are connected via pairs of N—H⋯O interactions into centrosymmetric dimers. Additionally, π–π stacking interactions link molecules into chains parallel to the a axis with short C⋯C distances being observed between the phenyl and thiocarbonyl [3.236 (8) Å] groups and between the thiocarbonyl and carbonyl [3.351 (4) Å] groups of stacked molecules. |
---|