Cargando…
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate
In the title compound, C(12)H(11)N(3)O(3)·2H(2)O, the dihedral angle formed by the planes of the pyridine and the furan rings of the organic carbohydrazide molecule is 4.66 (7)°. In the crystal, these molecules form stacks along the b-axis direction, neighbouring molecules within each stack being...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793823/ https://www.ncbi.nlm.nih.gov/pubmed/24109410 http://dx.doi.org/10.1107/S1600536813020114 |
_version_ | 1782287126778347520 |
---|---|
author | Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra |
author_facet | Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra |
author_sort | Prasanna, M. K. |
collection | PubMed |
description | In the title compound, C(12)H(11)N(3)O(3)·2H(2)O, the dihedral angle formed by the planes of the pyridine and the furan rings of the organic carbohydrazide molecule is 4.66 (7)°. In the crystal, these molecules form stacks along the b-axis direction, neighbouring molecules within each stack being related by inversion and the shortest distance between the centroids of the pyridine and furan rings being 3.714 (1) Å. Molecules from neighboring stacks are linked by pairs of N—H⋯O hydrogen bonds. The water molecules fill the channels between the stacks being linked by O—H⋯O hydrogen bonds into helices along [010]. Besides this, water molecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the carbohydrazide molecules, thus forming a three-dimensional network, augmented by weak C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3793823 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37938232013-10-09 N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(11)N(3)O(3)·2H(2)O, the dihedral angle formed by the planes of the pyridine and the furan rings of the organic carbohydrazide molecule is 4.66 (7)°. In the crystal, these molecules form stacks along the b-axis direction, neighbouring molecules within each stack being related by inversion and the shortest distance between the centroids of the pyridine and furan rings being 3.714 (1) Å. Molecules from neighboring stacks are linked by pairs of N—H⋯O hydrogen bonds. The water molecules fill the channels between the stacks being linked by O—H⋯O hydrogen bonds into helices along [010]. Besides this, water molecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the carbohydrazide molecules, thus forming a three-dimensional network, augmented by weak C—H⋯O interactions. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793823/ /pubmed/24109410 http://dx.doi.org/10.1107/S1600536813020114 Text en © Prasanna et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title |
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title_full |
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title_fullStr |
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title_full_unstemmed |
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title_short |
N′-{(E)-[5-(Hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
title_sort | n′-{(e)-[5-(hydroxymethyl)furan-2-yl]methylidene}pyridine-4-carbohydrazide dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793823/ https://www.ncbi.nlm.nih.gov/pubmed/24109410 http://dx.doi.org/10.1107/S1600536813020114 |
work_keys_str_mv | AT prasannamk ne5hydroxymethylfuran2ylmethylidenepyridine4carbohydrazidedihydrate AT sithambaresanm ne5hydroxymethylfuran2ylmethylidenepyridine4carbohydrazidedihydrate AT pradeepkumark ne5hydroxymethylfuran2ylmethylidenepyridine4carbohydrazidedihydrate AT kurupmrprathapachandra ne5hydroxymethylfuran2ylmethylidenepyridine4carbohydrazidedihydrate |