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1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione
In the title compound, C(39)H(36)N(2)O(4)S, the piperidine ring adopts a twisted half-chair conformation. In the pyrrolothiazole fused-ring system, the pyrrole ring adopts an envelope conformation (with the C atom bound to the thiazole ring being the flap atom) and the thiazole ring also exhibit...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793825/ https://www.ncbi.nlm.nih.gov/pubmed/24109412 http://dx.doi.org/10.1107/S1600536813020084 |
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author | Almansour, Abulrahman I. Suresh Kumar, Raju Arumugam, Natarajan Nagalakshmi, R. A. Suresh, J. |
author_facet | Almansour, Abulrahman I. Suresh Kumar, Raju Arumugam, Natarajan Nagalakshmi, R. A. Suresh, J. |
author_sort | Almansour, Abulrahman I. |
collection | PubMed |
description | In the title compound, C(39)H(36)N(2)O(4)S, the piperidine ring adopts a twisted half-chair conformation. In the pyrrolothiazole fused-ring system, the pyrrole ring adopts an envelope conformation (with the C atom bound to the thiazole ring being the flap atom) and the thiazole ring also exhibits an envelope conformation (with the N atom bound to the pyrrole ring as the flap). The molecular structure features a weak intramolecular C—H⋯O interaction. In the crystal, a C—H⋯O interaction forms a linear chain along the diagonal of the ac plane, generating a C(14) graph-set motif. A weak C—H⋯π interaction also occurs. |
format | Online Article Text |
id | pubmed-3793825 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37938252013-10-09 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione Almansour, Abulrahman I. Suresh Kumar, Raju Arumugam, Natarajan Nagalakshmi, R. A. Suresh, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(39)H(36)N(2)O(4)S, the piperidine ring adopts a twisted half-chair conformation. In the pyrrolothiazole fused-ring system, the pyrrole ring adopts an envelope conformation (with the C atom bound to the thiazole ring being the flap atom) and the thiazole ring also exhibits an envelope conformation (with the N atom bound to the pyrrole ring as the flap). The molecular structure features a weak intramolecular C—H⋯O interaction. In the crystal, a C—H⋯O interaction forms a linear chain along the diagonal of the ac plane, generating a C(14) graph-set motif. A weak C—H⋯π interaction also occurs. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793825/ /pubmed/24109412 http://dx.doi.org/10.1107/S1600536813020084 Text en © Almansour et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Almansour, Abulrahman I. Suresh Kumar, Raju Arumugam, Natarajan Nagalakshmi, R. A. Suresh, J. 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title | 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title_full | 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title_fullStr | 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title_full_unstemmed | 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title_short | 1′′-Allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1H)-dione |
title_sort | 1′′-allyl-5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′,3′,5′,6′,7′,7a′-hexahydrodispiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′(1h)-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793825/ https://www.ncbi.nlm.nih.gov/pubmed/24109412 http://dx.doi.org/10.1107/S1600536813020084 |
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