(E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)

The title compound, C(25)H(29)ClO(4), adopts a trans conformation about the C=C double bond and the di­methyl­cyclo­hexenone rings both show an envelope conformation with the dimethyl-substituted C atom as the flap. In the mol­ecule, the hy­droxy and carbonyl groups form two intra­molecular O—H⋯O hy...

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Autores principales: Cha, Joo Hwan, Lee, Jae Kyun, Min, Sun-Joon, Cho, Yong Seo, Park, Junghwan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793826/
https://www.ncbi.nlm.nih.gov/pubmed/24109413
http://dx.doi.org/10.1107/S1600536813020357
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author Cha, Joo Hwan
Lee, Jae Kyun
Min, Sun-Joon
Cho, Yong Seo
Park, Junghwan
author_facet Cha, Joo Hwan
Lee, Jae Kyun
Min, Sun-Joon
Cho, Yong Seo
Park, Junghwan
author_sort Cha, Joo Hwan
collection PubMed
description The title compound, C(25)H(29)ClO(4), adopts a trans conformation about the C=C double bond and the di­methyl­cyclo­hexenone rings both show an envelope conformation with the dimethyl-substituted C atom as the flap. In the mol­ecule, the hy­droxy and carbonyl groups form two intra­molecular O—H⋯O hydrogen bonds typical for xanthene derivatives. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into chains running parallel to the a-axis direction.
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spelling pubmed-37938262013-10-09 (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one) Cha, Joo Hwan Lee, Jae Kyun Min, Sun-Joon Cho, Yong Seo Park, Junghwan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(29)ClO(4), adopts a trans conformation about the C=C double bond and the di­methyl­cyclo­hexenone rings both show an envelope conformation with the dimethyl-substituted C atom as the flap. In the mol­ecule, the hy­droxy and carbonyl groups form two intra­molecular O—H⋯O hydrogen bonds typical for xanthene derivatives. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into chains running parallel to the a-axis direction. International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793826/ /pubmed/24109413 http://dx.doi.org/10.1107/S1600536813020357 Text en © Cha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cha, Joo Hwan
Lee, Jae Kyun
Min, Sun-Joon
Cho, Yong Seo
Park, Junghwan
(E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title_full (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title_fullStr (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title_full_unstemmed (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title_short (E)-2,2′-[3-(4-Chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
title_sort (e)-2,2′-[3-(4-chloro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-di­methyl­cyclo­hex-2-en-1-one)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793826/
https://www.ncbi.nlm.nih.gov/pubmed/24109413
http://dx.doi.org/10.1107/S1600536813020357
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