(1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol

The title compound, C(16)H(28)O, was synthesized by three steps from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus atlantica). The mol­ecule is built up from fused six- and seven-membered ring...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, El karroumi, Jamal, El Ammari, Lahcen, Saadi, Mohamed, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793829/
https://www.ncbi.nlm.nih.gov/pubmed/24109416
http://dx.doi.org/10.1107/S1600536813020576
Descripción
Sumario:The title compound, C(16)H(28)O, was synthesized by three steps from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus atlantica). The mol­ecule is built up from fused six- and seven-membered rings and an appended three-membered ring. The six-membered ring has twist-boat conformation, whereas the seven-membered ring displays a chair conformation. In the crystal, mol­ecules are linked into chains propagating along the a-axis direction by O—H⋯O hydrogen bonds.

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