(1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol

The title compound, C(16)H(28)O, was synthesized by three steps from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus atlantica). The mol­ecule is built up from fused six- and seven-membered ring...

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Autores principales: Benharref, Ahmed, El karroumi, Jamal, El Ammari, Lahcen, Saadi, Mohamed, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793829/
https://www.ncbi.nlm.nih.gov/pubmed/24109416
http://dx.doi.org/10.1107/S1600536813020576
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author Benharref, Ahmed
El karroumi, Jamal
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_facet Benharref, Ahmed
El karroumi, Jamal
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_sort Benharref, Ahmed
collection PubMed
description The title compound, C(16)H(28)O, was synthesized by three steps from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus atlantica). The mol­ecule is built up from fused six- and seven-membered rings and an appended three-membered ring. The six-membered ring has twist-boat conformation, whereas the seven-membered ring displays a chair conformation. In the crystal, mol­ecules are linked into chains propagating along the a-axis direction by O—H⋯O hydrogen bonds.
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spelling pubmed-37938292013-10-09 (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol Benharref, Ahmed El karroumi, Jamal El Ammari, Lahcen Saadi, Mohamed Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(28)O, was synthesized by three steps from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus atlantica). The mol­ecule is built up from fused six- and seven-membered rings and an appended three-membered ring. The six-membered ring has twist-boat conformation, whereas the seven-membered ring displays a chair conformation. In the crystal, mol­ecules are linked into chains propagating along the a-axis direction by O—H⋯O hydrogen bonds. International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793829/ /pubmed/24109416 http://dx.doi.org/10.1107/S1600536813020576 Text en © Benharref et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Benharref, Ahmed
El karroumi, Jamal
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
(1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title_full (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title_fullStr (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title_full_unstemmed (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title_short (1S,3S,8R,10R,11R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
title_sort (1s,3s,8r,10r,11r)-3,7,7,10-tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodecan-11-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793829/
https://www.ncbi.nlm.nih.gov/pubmed/24109416
http://dx.doi.org/10.1107/S1600536813020576
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