Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one

The 12-membered cyclo­penta­[b]indole ring system in the title compound, C(13)H(13)NO(2), deviates only slightly from planarity (r.m.s. deviation = 0.051 Å). In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into sheets parallel to (100). The five-membered cyclopentanone ring is in...

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Detalles Bibliográficos
Autores principales: Lopchuk, Justin M., Gribble, Gordon W., Millikan, Sean P., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793830/
https://www.ncbi.nlm.nih.gov/pubmed/24109417
http://dx.doi.org/10.1107/S1600536813020527
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author Lopchuk, Justin M.
Gribble, Gordon W.
Millikan, Sean P.
Jasinski, Jerry P.
author_facet Lopchuk, Justin M.
Gribble, Gordon W.
Millikan, Sean P.
Jasinski, Jerry P.
author_sort Lopchuk, Justin M.
collection PubMed
description The 12-membered cyclo­penta­[b]indole ring system in the title compound, C(13)H(13)NO(2), deviates only slightly from planarity (r.m.s. deviation = 0.051 Å). In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into sheets parallel to (100). The five-membered cyclopentanone ring is in slightly distorted envelope conformation with the C atom bearing the hydroxy substituent as the flap.
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spelling pubmed-37938302013-10-09 Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one Lopchuk, Justin M. Gribble, Gordon W. Millikan, Sean P. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 12-membered cyclo­penta­[b]indole ring system in the title compound, C(13)H(13)NO(2), deviates only slightly from planarity (r.m.s. deviation = 0.051 Å). In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into sheets parallel to (100). The five-membered cyclopentanone ring is in slightly distorted envelope conformation with the C atom bearing the hydroxy substituent as the flap. International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793830/ /pubmed/24109417 http://dx.doi.org/10.1107/S1600536813020527 Text en © Lopchuk et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lopchuk, Justin M.
Gribble, Gordon W.
Millikan, Sean P.
Jasinski, Jerry P.
Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title_full Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title_fullStr Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title_full_unstemmed Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title_short Bruceolline J: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4H)-one
title_sort bruceolline j: 2-hy­droxy-3,3-dimethyl-2,3-di­hydro­cyclo­penta­[b]indol-1(4h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793830/
https://www.ncbi.nlm.nih.gov/pubmed/24109417
http://dx.doi.org/10.1107/S1600536813020527
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