N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate

The fused five- and six-membered rings in the title compound, C(17)H(16)ClN(3)O(3)S·0.5H(2)O, are practically coplanar, with the maximum deviation from the mean plane being 0.057 (3) Å for the C atom bound to the exocyclic N atom. The indazole system makes a dihedral angle of 66.18 (12)° with the pl...

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Autores principales: Chicha, Hakima, Kouakou, Assoman, Rakib, El Mostapha, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793831/
https://www.ncbi.nlm.nih.gov/pubmed/24109418
http://dx.doi.org/10.1107/S1600536813020606
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author Chicha, Hakima
Kouakou, Assoman
Rakib, El Mostapha
Saadi, Mohamed
El Ammari, Lahcen
author_facet Chicha, Hakima
Kouakou, Assoman
Rakib, El Mostapha
Saadi, Mohamed
El Ammari, Lahcen
author_sort Chicha, Hakima
collection PubMed
description The fused five- and six-membered rings in the title compound, C(17)H(16)ClN(3)O(3)S·0.5H(2)O, are practically coplanar, with the maximum deviation from the mean plane being 0.057 (3) Å for the C atom bound to the exocyclic N atom. The indazole system makes a dihedral angle of 66.18 (12)° with the plane through the benzene ring, and it is nearly perpendicular to the allyl group, as indicated by the N—N—C—C torsion angle of 79.2 (3)°. In the crystal, the water mol­ecule, lying on a twofold axis, forms O—H⋯N and accepts N—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds contribute to the formation of a chain along the b-axis direction.
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spelling pubmed-37938312013-10-09 N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate Chicha, Hakima Kouakou, Assoman Rakib, El Mostapha Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The fused five- and six-membered rings in the title compound, C(17)H(16)ClN(3)O(3)S·0.5H(2)O, are practically coplanar, with the maximum deviation from the mean plane being 0.057 (3) Å for the C atom bound to the exocyclic N atom. The indazole system makes a dihedral angle of 66.18 (12)° with the plane through the benzene ring, and it is nearly perpendicular to the allyl group, as indicated by the N—N—C—C torsion angle of 79.2 (3)°. In the crystal, the water mol­ecule, lying on a twofold axis, forms O—H⋯N and accepts N—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds contribute to the formation of a chain along the b-axis direction. International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793831/ /pubmed/24109418 http://dx.doi.org/10.1107/S1600536813020606 Text en © Chicha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chicha, Hakima
Kouakou, Assoman
Rakib, El Mostapha
Saadi, Mohamed
El Ammari, Lahcen
N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title_full N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title_fullStr N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title_full_unstemmed N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title_short N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
title_sort n-(2-allyl-4-chloro-2h-indazol-5-yl)-4-meth­oxy­benzene­sulfonamide hemi­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793831/
https://www.ncbi.nlm.nih.gov/pubmed/24109418
http://dx.doi.org/10.1107/S1600536813020606
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