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Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate

In the title compound, 2C(6)H(11)N(2) (+)·P(2)Se(8) (2−) or [EMIM](2)P(2)Se(8) (EMIM = 1-ethyl-3-methyl­imidazolium), the anions, located about inversion centers between EMIM cations, exhibit a cyclo­hexane-like chair conformation. The cations are found in columns along the a axis, with centroid–cen...

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Detalles Bibliográficos
Autores principales: Cody, Jason A., Alexander, Grant C. B., Guillot-Deudon, Catherine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793835/
https://www.ncbi.nlm.nih.gov/pubmed/24109422
http://dx.doi.org/10.1107/S1600536813020308
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author Cody, Jason A.
Alexander, Grant C. B.
Guillot-Deudon, Catherine
author_facet Cody, Jason A.
Alexander, Grant C. B.
Guillot-Deudon, Catherine
author_sort Cody, Jason A.
collection PubMed
description In the title compound, 2C(6)H(11)N(2) (+)·P(2)Se(8) (2−) or [EMIM](2)P(2)Se(8) (EMIM = 1-ethyl-3-methyl­imidazolium), the anions, located about inversion centers between EMIM cations, exhibit a cyclo­hexane-like chair conformation. The cations are found in columns along the a axis, with centroid–centroid distances of 3.8399 (3) and 4.7530 (2) Å. The observed P—Se distances and Se—P—Se angles agree with other salts of this anion.
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spelling pubmed-37938352013-10-09 Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate Cody, Jason A. Alexander, Grant C. B. Guillot-Deudon, Catherine Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(6)H(11)N(2) (+)·P(2)Se(8) (2−) or [EMIM](2)P(2)Se(8) (EMIM = 1-ethyl-3-methyl­imidazolium), the anions, located about inversion centers between EMIM cations, exhibit a cyclo­hexane-like chair conformation. The cations are found in columns along the a axis, with centroid–centroid distances of 3.8399 (3) and 4.7530 (2) Å. The observed P—Se distances and Se—P—Se angles agree with other salts of this anion. International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793835/ /pubmed/24109422 http://dx.doi.org/10.1107/S1600536813020308 Text en © Cody et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cody, Jason A.
Alexander, Grant C. B.
Guillot-Deudon, Catherine
Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title_full Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title_fullStr Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title_full_unstemmed Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title_short Bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
title_sort bis(1-ethyl-3-methyl­imidazolium) 3,6-diselanyl­idene-1,2,4,5-tetra­selena-3,6-diphospha­cyclo­hexane-3,6-di­selen­olate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793835/
https://www.ncbi.nlm.nih.gov/pubmed/24109422
http://dx.doi.org/10.1107/S1600536813020308
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