Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate

The title compound, C(21)H(15)O(4)P·0.5C(4)H(8)O, contains an ordered phosphane oxide in a general position and a tetra­hydro­furan solvent mol­ecule disordered about a twofold axis. All three aldehyde substituents are nearly coplanar with their attached benzene rings, with C—C—C—O torsion angles in...

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Detalles Bibliográficos
Autores principales: Kakoullis, James, Fronczek, Frank R., Maverick, Andrew W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793837/
https://www.ncbi.nlm.nih.gov/pubmed/24109424
http://dx.doi.org/10.1107/S1600536813020059
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author Kakoullis, James
Fronczek, Frank R.
Maverick, Andrew W.
author_facet Kakoullis, James
Fronczek, Frank R.
Maverick, Andrew W.
author_sort Kakoullis, James
collection PubMed
description The title compound, C(21)H(15)O(4)P·0.5C(4)H(8)O, contains an ordered phosphane oxide in a general position and a tetra­hydro­furan solvent mol­ecule disordered about a twofold axis. All three aldehyde substituents are nearly coplanar with their attached benzene rings, with C—C—C—O torsion angles in the range 1.64 (17)–4.24 (19)°. All three have different conformations with respect to the P=O group, one syn, one anti, and one gauche. Two of the aldehyde substituents form inter­molecular C—H⋯O contacts.
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spelling pubmed-37938372013-10-09 Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate Kakoullis, James Fronczek, Frank R. Maverick, Andrew W. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(15)O(4)P·0.5C(4)H(8)O, contains an ordered phosphane oxide in a general position and a tetra­hydro­furan solvent mol­ecule disordered about a twofold axis. All three aldehyde substituents are nearly coplanar with their attached benzene rings, with C—C—C—O torsion angles in the range 1.64 (17)–4.24 (19)°. All three have different conformations with respect to the P=O group, one syn, one anti, and one gauche. Two of the aldehyde substituents form inter­molecular C—H⋯O contacts. International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793837/ /pubmed/24109424 http://dx.doi.org/10.1107/S1600536813020059 Text en © Kakoullis Jr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kakoullis, James
Fronczek, Frank R.
Maverick, Andrew W.
Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title_full Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title_fullStr Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title_full_unstemmed Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title_short Tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
title_sort tris(4-formyl­phen­yl)phosphane oxide tetra­hydro­furan hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793837/
https://www.ncbi.nlm.nih.gov/pubmed/24109424
http://dx.doi.org/10.1107/S1600536813020059
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