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Spontaneous chiral resolution directed by symmetry restriction and π-π interaction
In order to understand and rationally construct homochiral self-assembled structures from racemic molecules, two novel crystalline metal-organic frameworks with chiral cavities were developed. The homochirality of the layers in both MOFs was achieved by forming strong coordinate bonds between the C(...
Autores principales: | Yu, Jin-Tao, Shi, Yan-Yan, Sun, Junliang, Lin, Jianhua, Huang, Zhi-Tang, Zheng, Qi-Yu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3796745/ https://www.ncbi.nlm.nih.gov/pubmed/24126555 http://dx.doi.org/10.1038/srep02947 |
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