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Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea
π-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluores...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3810720/ https://www.ncbi.nlm.nih.gov/pubmed/21500301 http://dx.doi.org/10.1002/marc.201100045 |
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author | Zhang, Kai Tieke, Bernd Vilela, Filipe Skabara, Peter J |
author_facet | Zhang, Kai Tieke, Bernd Vilela, Filipe Skabara, Peter J |
author_sort | Zhang, Kai |
collection | PubMed |
description | π-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) · g(−1). |
format | Online Article Text |
id | pubmed-3810720 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | WILEY-VCH Verlag |
record_format | MEDLINE/PubMed |
spelling | pubmed-38107202013-11-06 Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea Zhang, Kai Tieke, Bernd Vilela, Filipe Skabara, Peter J Macromol Rapid Commun Communications π-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) · g(−1). WILEY-VCH Verlag 2011-06-01 2011-04-15 /pmc/articles/PMC3810720/ /pubmed/21500301 http://dx.doi.org/10.1002/marc.201100045 Text en Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim http://creativecommons.org/licenses/by/2.5/ Re-use of this article is permitted in accordance with the Creative Commons Deed, Attribution 2.5, which does not permit commercial exploitation. |
spellingShingle | Communications Zhang, Kai Tieke, Bernd Vilela, Filipe Skabara, Peter J Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title | Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title_full | Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title_fullStr | Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title_full_unstemmed | Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title_short | Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrolea |
title_sort | conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrolea |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3810720/ https://www.ncbi.nlm.nih.gov/pubmed/21500301 http://dx.doi.org/10.1002/marc.201100045 |
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