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Elucidation of the regio- and chemoselectivity of enzymatic allylic oxidations with Pleurotus sapidus – conversion of selected spirocyclic terpenoids and computational analysis
Allylic oxidations of olefins to enones allow the efficient synthesis of value-added products from simple olefinic precursors like terpenes or terpenoids. Biocatalytic variants have a large potential for industrial applications, particularly in the pharmaceutical and food industry. Herein we report...
Autores principales: | Weidmann, Verena, Schaffrath, Mathias, Zorn, Holger, Rehbein, Julia, Maison, Wolfgang |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817473/ https://www.ncbi.nlm.nih.gov/pubmed/24204436 http://dx.doi.org/10.3762/bjoc.9.262 |
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