Gold(I)-catalyzed enantioselective cycloaddition reactions

In recent years there have been extraordinary developments of gold(I)-catalyzed enantioselective processes. This includes progress in the area of cycloaddition reactions, which are of particular interest due to their potential for the rapid construction of optically active cyclic products. In this a...

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Detalles Bibliográficos
Autores principales: López, Fernando, Mascareñas, José L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817474/
https://www.ncbi.nlm.nih.gov/pubmed/24204438
http://dx.doi.org/10.3762/bjoc.9.264
Descripción
Sumario:In recent years there have been extraordinary developments of gold(I)-catalyzed enantioselective processes. This includes progress in the area of cycloaddition reactions, which are of particular interest due to their potential for the rapid construction of optically active cyclic products. In this article we will summarize some of the most remarkable examples, emphasizing reaction mechanisms and key intermediates involved in the processes.

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