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Synthesis of enantiomerically pure (2S,3S)-5,5,5-trifluoroisoleucine and (2R,3S)-5,5,5-trifluoro-allo-isoleucine
A practical route for the stereoselective synthesis of (2S,3S)-5,5,5-trifluoroisoleucine (L-5-F(3)Ile) and (2R,3S)-5,5,5-trifluoro-allo-isoleucine (D-5-F(3)-allo-Ile) was developed. The hydrophobicity of L-5-F(3)Ile was examined and it was incorporated into a model peptide via solid phase peptide sy...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817528/ https://www.ncbi.nlm.nih.gov/pubmed/24204411 http://dx.doi.org/10.3762/bjoc.9.236 |