Cargando…

Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

[Image: see text] A molecular proton reduction catalyst [FeFe](dcbdt)(CO)(6) (1, dcbdt = 1,4-dicarboxylbenzene-2,3-dithiolate) with structural similarities to [FeFe]-hydrogenase active sites has been incorporated into a highly robust Zr(IV)-based metal–organic framework (MOF) by postsynthetic exchan...

Descripción completa

Detalles Bibliográficos
Autores principales: Pullen, Sonja, Fei, Honghan, Orthaber, Andreas, Cohen, Seth M., Ott, Sascha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3829681/
https://www.ncbi.nlm.nih.gov/pubmed/24116734
http://dx.doi.org/10.1021/ja407176p