Application of alizarin colorimetric measurements for quantification of amine extraction by model food simulants from epoxy polymer

A simple and straightforward method has been proposed for quantification of residual amine in cured epoxy resin. Non-bounded triethylenetetramine was extracted from epoxy polymer and determined via spectrophotometry using alizarin chromophore. Four solvents commonly used as food simulants, namely water, 95% ethanol, 10% ethanol and 3% acetic acid were examined. Released amine induces changes in the absorption spectrum of alizarin, by decreasing the intensity of the maximum at 430 nm band and mutually increasing the 527 nm band. These changes were proportional to the amounts of amine concentration in samples. The statistical significance of obtained calibration curves was validated. Among studied solvents, the highest amine release was observed for water solution and 3% acetic acid, that is approximately 7% w/w. The maximal amount of residual amine extracted with 95% ethanol was about 1.25%, while for 10% ethanol this amount was 2%. The effect of aging of the samples and exposure to artificial sunlight were also examined. The proposed method has been proven to be fast, low cost and directly applicable for analysis of typical epoxy resins.