Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex

A library of 1,2,3-triazoles was synthesized from diverse alkynes and azides using catalytic amounts of silver chloride instead of copper compounds. In addition, a novel “abnormal” silver N-heterocyclic carbene complex was tested as catalyst in this process. The results suggest that the reaction req...

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Autores principales: Ortega-Arizmendi, Aldo I., Aldeco-Pérez, Eugenia, Cuevas-Yañez, Erick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2013
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3836375/
https://www.ncbi.nlm.nih.gov/pubmed/24307866
http://dx.doi.org/10.1155/2013/186537
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author Ortega-Arizmendi, Aldo I.
Aldeco-Pérez, Eugenia
Cuevas-Yañez, Erick
author_facet Ortega-Arizmendi, Aldo I.
Aldeco-Pérez, Eugenia
Cuevas-Yañez, Erick
author_sort Ortega-Arizmendi, Aldo I.
collection PubMed
description A library of 1,2,3-triazoles was synthesized from diverse alkynes and azides using catalytic amounts of silver chloride instead of copper compounds. In addition, a novel “abnormal” silver N-heterocyclic carbene complex was tested as catalyst in this process. The results suggest that the reaction requires only 0.5% of silver complex, affording 1,2,3-triazoles in good yields.
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spelling pubmed-38363752013-12-04 Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex Ortega-Arizmendi, Aldo I. Aldeco-Pérez, Eugenia Cuevas-Yañez, Erick ScientificWorldJournal Research Article A library of 1,2,3-triazoles was synthesized from diverse alkynes and azides using catalytic amounts of silver chloride instead of copper compounds. In addition, a novel “abnormal” silver N-heterocyclic carbene complex was tested as catalyst in this process. The results suggest that the reaction requires only 0.5% of silver complex, affording 1,2,3-triazoles in good yields. Hindawi Publishing Corporation 2013-11-06 /pmc/articles/PMC3836375/ /pubmed/24307866 http://dx.doi.org/10.1155/2013/186537 Text en Copyright © 2013 Aldo I. Ortega-Arizmendi et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Ortega-Arizmendi, Aldo I.
Aldeco-Pérez, Eugenia
Cuevas-Yañez, Erick
Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title_full Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title_fullStr Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title_full_unstemmed Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title_short Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
title_sort alkyne-azide cycloaddition catalyzed by silver chloride and “abnormal” silver n-heterocyclic carbene complex
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3836375/
https://www.ncbi.nlm.nih.gov/pubmed/24307866
http://dx.doi.org/10.1155/2013/186537
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