Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities

A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framew...

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Detalles Bibliográficos
Autores principales: Zhang, Da-Shuai, Chang, Ze, Li, Yi-Fan, Jiang, Zhong-Yi, Xuan, Zhi-Hong, Zhang, Ying-Hui, Li, Jian-Rong, Chen, Qiang, Hu, Tong-Liang, Bu, Xian-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3837364/
https://www.ncbi.nlm.nih.gov/pubmed/24264725
http://dx.doi.org/10.1038/srep03312
Descripción
Sumario:A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framework stabilities and adsorption capacities towards H(2)/CO(2) were enhanced significantly. This consequence can be well interpreted by theoretical studies of these MOFs structures. In addition, one of these MOFs TKL-107 was used to fabricate mixed matrix membranes, which exhibit great potential for the application of CO(2) separation.

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