Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities

A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framew...

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Autores principales: Zhang, Da-Shuai, Chang, Ze, Li, Yi-Fan, Jiang, Zhong-Yi, Xuan, Zhi-Hong, Zhang, Ying-Hui, Li, Jian-Rong, Chen, Qiang, Hu, Tong-Liang, Bu, Xian-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3837364/
https://www.ncbi.nlm.nih.gov/pubmed/24264725
http://dx.doi.org/10.1038/srep03312
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author Zhang, Da-Shuai
Chang, Ze
Li, Yi-Fan
Jiang, Zhong-Yi
Xuan, Zhi-Hong
Zhang, Ying-Hui
Li, Jian-Rong
Chen, Qiang
Hu, Tong-Liang
Bu, Xian-He
author_facet Zhang, Da-Shuai
Chang, Ze
Li, Yi-Fan
Jiang, Zhong-Yi
Xuan, Zhi-Hong
Zhang, Ying-Hui
Li, Jian-Rong
Chen, Qiang
Hu, Tong-Liang
Bu, Xian-He
author_sort Zhang, Da-Shuai
collection PubMed
description A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framework stabilities and adsorption capacities towards H(2)/CO(2) were enhanced significantly. This consequence can be well interpreted by theoretical studies of these MOFs structures. In addition, one of these MOFs TKL-107 was used to fabricate mixed matrix membranes, which exhibit great potential for the application of CO(2) separation.
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spelling pubmed-38373642013-11-22 Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities Zhang, Da-Shuai Chang, Ze Li, Yi-Fan Jiang, Zhong-Yi Xuan, Zhi-Hong Zhang, Ying-Hui Li, Jian-Rong Chen, Qiang Hu, Tong-Liang Bu, Xian-He Sci Rep Article A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framework stabilities and adsorption capacities towards H(2)/CO(2) were enhanced significantly. This consequence can be well interpreted by theoretical studies of these MOFs structures. In addition, one of these MOFs TKL-107 was used to fabricate mixed matrix membranes, which exhibit great potential for the application of CO(2) separation. Nature Publishing Group 2013-11-22 /pmc/articles/PMC3837364/ /pubmed/24264725 http://dx.doi.org/10.1038/srep03312 Text en Copyright © 2013, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-sa/3.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-ShareALike 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-sa/3.0/
spellingShingle Article
Zhang, Da-Shuai
Chang, Ze
Li, Yi-Fan
Jiang, Zhong-Yi
Xuan, Zhi-Hong
Zhang, Ying-Hui
Li, Jian-Rong
Chen, Qiang
Hu, Tong-Liang
Bu, Xian-He
Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title_full Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title_fullStr Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title_full_unstemmed Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title_short Fluorous Metal-Organic Frameworks with Enhanced Stability and High H(2)/CO(2) Storage Capacities
title_sort fluorous metal-organic frameworks with enhanced stability and high h(2)/co(2) storage capacities
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3837364/
https://www.ncbi.nlm.nih.gov/pubmed/24264725
http://dx.doi.org/10.1038/srep03312
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