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Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement
Flavoproteins catalyze a diversity of fundamental redox reactions and are one of the most studied enzyme families(1,2). As monooxygenases, they are universally thought to control oxygenation by means of a peroxyflavin species that transfers a single atom of molecular oxygen to an organic substrate(1...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3844076/ https://www.ncbi.nlm.nih.gov/pubmed/24162851 http://dx.doi.org/10.1038/nature12643 |