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Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum

The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis....

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Detalles Bibliográficos
Autores principales: Li, Lili, Wang, Xiaoning, Sun, Jinsheng, Zhang, Yichen, Qin, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3852807/
https://www.ncbi.nlm.nih.gov/pubmed/24350245
http://dx.doi.org/10.1155/2013/162907
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author Li, Lili
Wang, Xiaoning
Sun, Jinsheng
Zhang, Yichen
Qin, Song
author_facet Li, Lili
Wang, Xiaoning
Sun, Jinsheng
Zhang, Yichen
Qin, Song
author_sort Li, Lili
collection PubMed
description The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis. The major mass loss due to devolatilization started at 154 and 162°C at the heating rate of 10°C min(−1) for Artemisia annua and Chenopodium glaucum, respectively. The results showed that the average activation energies of Artemisia annua and Chenopodium glaucum were 169.69 and 170.48 kJ mol(−1), respectively. Furthermore, the activation energy changed while the conversion rate increased, and the frequency factor k (0) decreased greatly while the activation energy decreased. The results also indicated that the devolatilization of the two coastal plant species underwent a set of first-order reactions and could be expressed by the DAEM. Additionally, a simplified mathematical model was proposed to facilitate the prediction of devolatilization curves.
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spelling pubmed-38528072013-12-12 Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum Li, Lili Wang, Xiaoning Sun, Jinsheng Zhang, Yichen Qin, Song Biomed Res Int Research Article The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis. The major mass loss due to devolatilization started at 154 and 162°C at the heating rate of 10°C min(−1) for Artemisia annua and Chenopodium glaucum, respectively. The results showed that the average activation energies of Artemisia annua and Chenopodium glaucum were 169.69 and 170.48 kJ mol(−1), respectively. Furthermore, the activation energy changed while the conversion rate increased, and the frequency factor k (0) decreased greatly while the activation energy decreased. The results also indicated that the devolatilization of the two coastal plant species underwent a set of first-order reactions and could be expressed by the DAEM. Additionally, a simplified mathematical model was proposed to facilitate the prediction of devolatilization curves. Hindawi Publishing Corporation 2013 2013-11-19 /pmc/articles/PMC3852807/ /pubmed/24350245 http://dx.doi.org/10.1155/2013/162907 Text en Copyright © 2013 Lili Li et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Li, Lili
Wang, Xiaoning
Sun, Jinsheng
Zhang, Yichen
Qin, Song
Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title_full Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title_fullStr Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title_full_unstemmed Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title_short Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
title_sort pyrolytic and kinetic analysis of two coastal plant species: artemisia annua and chenopodium glaucum
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3852807/
https://www.ncbi.nlm.nih.gov/pubmed/24350245
http://dx.doi.org/10.1155/2013/162907
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