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Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis....
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Hindawi Publishing Corporation
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3852807/ https://www.ncbi.nlm.nih.gov/pubmed/24350245 http://dx.doi.org/10.1155/2013/162907 |
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author | Li, Lili Wang, Xiaoning Sun, Jinsheng Zhang, Yichen Qin, Song |
author_facet | Li, Lili Wang, Xiaoning Sun, Jinsheng Zhang, Yichen Qin, Song |
author_sort | Li, Lili |
collection | PubMed |
description | The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis. The major mass loss due to devolatilization started at 154 and 162°C at the heating rate of 10°C min(−1) for Artemisia annua and Chenopodium glaucum, respectively. The results showed that the average activation energies of Artemisia annua and Chenopodium glaucum were 169.69 and 170.48 kJ mol(−1), respectively. Furthermore, the activation energy changed while the conversion rate increased, and the frequency factor k (0) decreased greatly while the activation energy decreased. The results also indicated that the devolatilization of the two coastal plant species underwent a set of first-order reactions and could be expressed by the DAEM. Additionally, a simplified mathematical model was proposed to facilitate the prediction of devolatilization curves. |
format | Online Article Text |
id | pubmed-3852807 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | Hindawi Publishing Corporation |
record_format | MEDLINE/PubMed |
spelling | pubmed-38528072013-12-12 Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum Li, Lili Wang, Xiaoning Sun, Jinsheng Zhang, Yichen Qin, Song Biomed Res Int Research Article The large amount of coastal plant species available makes them ideal candidates for energy production. In this study, thermogravimetric analysis was used to evaluate the fuel properties of two coastal plant species, and the distributed activation energy model (DAEM) was employed in kinetic analysis. The major mass loss due to devolatilization started at 154 and 162°C at the heating rate of 10°C min(−1) for Artemisia annua and Chenopodium glaucum, respectively. The results showed that the average activation energies of Artemisia annua and Chenopodium glaucum were 169.69 and 170.48 kJ mol(−1), respectively. Furthermore, the activation energy changed while the conversion rate increased, and the frequency factor k (0) decreased greatly while the activation energy decreased. The results also indicated that the devolatilization of the two coastal plant species underwent a set of first-order reactions and could be expressed by the DAEM. Additionally, a simplified mathematical model was proposed to facilitate the prediction of devolatilization curves. Hindawi Publishing Corporation 2013 2013-11-19 /pmc/articles/PMC3852807/ /pubmed/24350245 http://dx.doi.org/10.1155/2013/162907 Text en Copyright © 2013 Lili Li et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Li, Lili Wang, Xiaoning Sun, Jinsheng Zhang, Yichen Qin, Song Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum |
title | Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
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title_full | Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
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title_fullStr | Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
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title_full_unstemmed | Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
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title_short | Pyrolytic and Kinetic Analysis of Two Coastal Plant Species: Artemisia annua and Chenopodium glaucum
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title_sort | pyrolytic and kinetic analysis of two coastal plant species: artemisia annua and chenopodium glaucum |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3852807/ https://www.ncbi.nlm.nih.gov/pubmed/24350245 http://dx.doi.org/10.1155/2013/162907 |
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