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Enhanced thermoelectric performance of Nb-doped SrTiO(3) by nano-inclusion with low thermal conductivity

Authors reported an effective path to increase the electrical conductivity while to decrease the thermal conductivity, and thus to enhance the ZT value by nano-inclusions. By this method, the ZT value of Nb-doped SrTiO(3) was enhanced 9-fold by yttria stabilized zirconia (YSZ) nano-inclusions. YSZ i...

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Detalles Bibliográficos
Autores principales: Wang, Ning, Chen, Haijun, He, Hongcai, Norimatsu, Wataru, Kusunoki, Michiko, Koumoto, Kunihito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3856403/
https://www.ncbi.nlm.nih.gov/pubmed/24316665
http://dx.doi.org/10.1038/srep03449
Descripción
Sumario:Authors reported an effective path to increase the electrical conductivity while to decrease the thermal conductivity, and thus to enhance the ZT value by nano-inclusions. By this method, the ZT value of Nb-doped SrTiO(3) was enhanced 9-fold by yttria stabilized zirconia (YSZ) nano-inclusions. YSZ inclusions, located inside grain and in triple junction, can reduce the thermal conductivity by effective interface phonon scattering, enhance the electrical conductivity by promoting the abnormal grain growth, and thus lead to the obvious enhancement of ZT value, which strongly suggests that, it is possible to not only reduce the thermal conductivity, but also increase the electrical conductivity by nano-inclusions with low thermal conductivity. This study will give some useful enlightenment to the preparation of high-performance oxide thermoelectric materials.