Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange

[Image: see text] An ‘arene exchange’ approach has been successfully applied for the first time to the synthesis of Ru(II)-based ‘tethered’ reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series o...

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Autores principales: Soni, Rina, Jolley, Katherine E., Clarkson, Guy J., Wills, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3856772/
https://www.ncbi.nlm.nih.gov/pubmed/24070028
http://dx.doi.org/10.1021/ol4024979
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author Soni, Rina
Jolley, Katherine E.
Clarkson, Guy J.
Wills, Martin
author_facet Soni, Rina
Jolley, Katherine E.
Clarkson, Guy J.
Wills, Martin
author_sort Soni, Rina
collection PubMed
description [Image: see text] An ‘arene exchange’ approach has been successfully applied for the first time to the synthesis of Ru(II)-based ‘tethered’ reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.
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spelling pubmed-38567722013-12-09 Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange Soni, Rina Jolley, Katherine E. Clarkson, Guy J. Wills, Martin Org Lett [Image: see text] An ‘arene exchange’ approach has been successfully applied for the first time to the synthesis of Ru(II)-based ‘tethered’ reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones. American Chemical Society 2013-09-26 2013-10-04 /pmc/articles/PMC3856772/ /pubmed/24070028 http://dx.doi.org/10.1021/ol4024979 Text en Copyright © 2013 American Chemical Society Terms of Use (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html)
spellingShingle Soni, Rina
Jolley, Katherine E.
Clarkson, Guy J.
Wills, Martin
Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title_full Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title_fullStr Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title_full_unstemmed Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title_short Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
title_sort direct formation of tethered ru(ii) catalysts using arene exchange
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3856772/
https://www.ncbi.nlm.nih.gov/pubmed/24070028
http://dx.doi.org/10.1021/ol4024979
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