Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings

Sterically crowded diimine ligands with five aryl rings were prepared in one step in good yields using a micro-flow technique. X-ray crystallographic analysis revealed the detailed structure of the bulky ligands. The nickel complexes prepared from the ligands exerted high polymerization activity in...

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Autores principales: Fuse, Shinichiro, Tanabe, Nobutake, Tannna, Akio, Konishi, Yohei, Takahashi, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869212/
https://www.ncbi.nlm.nih.gov/pubmed/24367397
http://dx.doi.org/10.3762/bjoc.9.268
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author Fuse, Shinichiro
Tanabe, Nobutake
Tannna, Akio
Konishi, Yohei
Takahashi, Takashi
author_facet Fuse, Shinichiro
Tanabe, Nobutake
Tannna, Akio
Konishi, Yohei
Takahashi, Takashi
author_sort Fuse, Shinichiro
collection PubMed
description Sterically crowded diimine ligands with five aryl rings were prepared in one step in good yields using a micro-flow technique. X-ray crystallographic analysis revealed the detailed structure of the bulky ligands. The nickel complexes prepared from the ligands exerted high polymerization activity in the ethylene homopolymerization and copolymerization of ethylene with polar monomers.
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spelling pubmed-38692122013-12-23 Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings Fuse, Shinichiro Tanabe, Nobutake Tannna, Akio Konishi, Yohei Takahashi, Takashi Beilstein J Org Chem Full Research Paper Sterically crowded diimine ligands with five aryl rings were prepared in one step in good yields using a micro-flow technique. X-ray crystallographic analysis revealed the detailed structure of the bulky ligands. The nickel complexes prepared from the ligands exerted high polymerization activity in the ethylene homopolymerization and copolymerization of ethylene with polar monomers. Beilstein-Institut 2013-11-01 /pmc/articles/PMC3869212/ /pubmed/24367397 http://dx.doi.org/10.3762/bjoc.9.268 Text en Copyright © 2013, Fuse et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Fuse, Shinichiro
Tanabe, Nobutake
Tannna, Akio
Konishi, Yohei
Takahashi, Takashi
Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title_full Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title_fullStr Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title_full_unstemmed Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title_short Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
title_sort micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869212/
https://www.ncbi.nlm.nih.gov/pubmed/24367397
http://dx.doi.org/10.3762/bjoc.9.268
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