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Oxidative 3,3,3-trifluoropropylation of arylaldehydes

A reaction between (E)-trimethyl(3,3,3-trifluoroprop-1-en-1-yl)silane (1) and arylaldehydes 2 was triggered by fluoride anions to afford aryl 3,3,3-trifluoropropyl ketones 3 in moderate to good yield. A mechanistic study of this reaction indicated that it occurred via an allyl alkoxide (4). A subseq...

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Detalles Bibliográficos
Autores principales:	Ikeda, Akari, Omote, Masaaki, Nomura, Shiho, Tanaka, Miyuu, Tarui, Atsushi, Sato, Kazuyuki, Ando, Akira
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2013
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869248/ https://www.ncbi.nlm.nih.gov/pubmed/24367408 http://dx.doi.org/10.3762/bjoc.9.279

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