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The total synthesis of D-chalcose and its C-3 epimer

We completed a new and efficient synthesis of D-chalcose (I) and the first synthesis of its C-3 epimer (I′) in nine steps with overall yields of 23% and 24%, respectively. The key steps in the sequence were the formation of the stereocenter on C3 via Grignard reaction, the introduction of the stereo...

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Detalles Bibliográficos
Autores principales:	Sun, Jun, Fan, Song, Wang, Zhan, Zhang, Guoning, Bao, Kai, Zhang, Weige
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2013
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869251/ https://www.ncbi.nlm.nih.gov/pubmed/24367425 http://dx.doi.org/10.3762/bjoc.9.296

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