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Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis
Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers. A catalytic amount of copper triflate was identified as the significant additive in promoting this transformation. Both aromatic and aliphatic alkynes are s...
Autores principales: | Xi, Yumeng, Dong, Boliang, Shi, Xiaodong |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869262/ https://www.ncbi.nlm.nih.gov/pubmed/24367417 http://dx.doi.org/10.3762/bjoc.9.288 |
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