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Bidirectional cross metathesis and ring-closing metathesis/ring opening of a C(2)-symmetric building block: a strategy for the synthesis of decanolide natural products
Starting from the conveniently available ex-chiral pool building block (R,R)-hexa-1,5-diene-3,4-diol, the ten-membered ring lactones stagonolide E and curvulide A were synthesized using a bidirectional olefin-metathesis functionalization of the terminal double bonds. Key steps are (i) a site-selecti...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869341/ https://www.ncbi.nlm.nih.gov/pubmed/24367418 http://dx.doi.org/10.3762/bjoc.9.289 |