Crystal design using multipolar electrostatic interactions: A concept study for organic electronics

Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is mainly controlled by electrostatic interactions. T...

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Detalles Bibliográficos
Autores principales: Kirsch, Peer, Tong, Qiong, Untenecker, Harald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869368/
https://www.ncbi.nlm.nih.gov/pubmed/24367401
http://dx.doi.org/10.3762/bjoc.9.272
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author Kirsch, Peer
Tong, Qiong
Untenecker, Harald
author_facet Kirsch, Peer
Tong, Qiong
Untenecker, Harald
author_sort Kirsch, Peer
collection PubMed
description Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is mainly controlled by electrostatic interactions. This type of packing offers an advantage for organic semiconductors, because it allows more isotropic charge transport compared to the “herring bone” stacking observed for other acenes.
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spelling pubmed-38693682013-12-23 Crystal design using multipolar electrostatic interactions: A concept study for organic electronics Kirsch, Peer Tong, Qiong Untenecker, Harald Beilstein J Org Chem Full Research Paper Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is mainly controlled by electrostatic interactions. This type of packing offers an advantage for organic semiconductors, because it allows more isotropic charge transport compared to the “herring bone” stacking observed for other acenes. Beilstein-Institut 2013-11-05 /pmc/articles/PMC3869368/ /pubmed/24367401 http://dx.doi.org/10.3762/bjoc.9.272 Text en Copyright © 2013, Kirsch et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kirsch, Peer
Tong, Qiong
Untenecker, Harald
Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title_full Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title_fullStr Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title_full_unstemmed Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title_short Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
title_sort crystal design using multipolar electrostatic interactions: a concept study for organic electronics
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869368/
https://www.ncbi.nlm.nih.gov/pubmed/24367401
http://dx.doi.org/10.3762/bjoc.9.272
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