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A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations

The constants of the extraction equilibrium and the distribution for dichloromethane as an organic solvent having low dielectric constant of metal cations with chiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), ohydroxybenzaldehydene-( S)-2-amino-3-phenyl-propanol (II), benzaldehy...

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Autores principales: Topal, Giray, Tümerdem, Recep, Basaran, Ismet, Gümüş, Arzu, Cakir, Umit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3871894/
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author Topal, Giray
Tümerdem, Recep
Basaran, Ismet
Gümüş, Arzu
Cakir, Umit
author_facet Topal, Giray
Tümerdem, Recep
Basaran, Ismet
Gümüş, Arzu
Cakir, Umit
author_sort Topal, Giray
collection PubMed
description The constants of the extraction equilibrium and the distribution for dichloromethane as an organic solvent having low dielectric constant of metal cations with chiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), ohydroxybenzaldehydene-( S)-2-amino-3-phenyl-propanol (II), benzaldehydene-(S)-2- amino-3-methylbutanol (III) with anionic dyes [4-(2-pyridylazo)-resorcinol mono sodium monohydrate (NaPar), sodium picrat (NaPic) and potassium picrat (KPic)] and some heavy metal chlorides were determined at 25 ºC. All the ligands have given strongest complexation for NaPar. In contrast, similar behaviour for both alkali metal picrates is not apparent in the complexation of corresponding ligands.
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spelling pubmed-38718942013-12-26 A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations Topal, Giray Tümerdem, Recep Basaran, Ismet Gümüş, Arzu Cakir, Umit Int J Mol Sci Full Research Paper The constants of the extraction equilibrium and the distribution for dichloromethane as an organic solvent having low dielectric constant of metal cations with chiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), ohydroxybenzaldehydene-( S)-2-amino-3-phenyl-propanol (II), benzaldehydene-(S)-2- amino-3-methylbutanol (III) with anionic dyes [4-(2-pyridylazo)-resorcinol mono sodium monohydrate (NaPar), sodium picrat (NaPic) and potassium picrat (KPic)] and some heavy metal chlorides were determined at 25 ºC. All the ligands have given strongest complexation for NaPar. In contrast, similar behaviour for both alkali metal picrates is not apparent in the complexation of corresponding ligands. Molecular Diversity Preservation International (MDPI) 2007-09-04 /pmc/articles/PMC3871894/ Text en © 2007 by MDPI Reproduction is permitted for noncommercial purposes.
spellingShingle Full Research Paper
Topal, Giray
Tümerdem, Recep
Basaran, Ismet
Gümüş, Arzu
Cakir, Umit
A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title_full A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title_fullStr A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title_full_unstemmed A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title_short A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
title_sort study of complexation-ability of neutral schiff bases to some metal cations
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3871894/
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