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Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect

At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference i...

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Autores principales: Zhou, Xuan, Zhang, Zhidong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3876101/
https://www.ncbi.nlm.nih.gov/pubmed/24351807
http://dx.doi.org/10.3390/ijms141224135
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author Zhou, Xuan
Zhang, Zhidong
author_facet Zhou, Xuan
Zhang, Zhidong
author_sort Zhou, Xuan
collection PubMed
description At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference iterative method. Our results show that with the cell gap decreasing, the core of the defect explodes, and the biaxiality propagates inside the cell. At a critical value of d(c)* ≈ 9ξ (where ξ is the characteristic length for order-parameter changes), the exchange solution is stable, while the defect core solution becomes metastable. Comparing to the case with no initial disclination, the value at which the exchange solution becomes stable increases relatively. At a critical separation of d(c) ≈ 6ξ, the system undergoes a structural transition, and the defect core merges into a biaxial layer with large biaxiality. For weak anchoring boundary conditions, a similar structural transition takes place at a relative lower critical value. Because of the weakened frustration, the asymmetric boundary conditions repel the defect to the weak anchoring boundary and have a relatively lower critical value of d(a), where the shape of the defect deforms. Further, the response time between two very close cell gaps is about tens of microseconds, and the response becomes slower as the defect explodes.
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spelling pubmed-38761012013-12-31 Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect Zhou, Xuan Zhang, Zhidong Int J Mol Sci Article At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference iterative method. Our results show that with the cell gap decreasing, the core of the defect explodes, and the biaxiality propagates inside the cell. At a critical value of d(c)* ≈ 9ξ (where ξ is the characteristic length for order-parameter changes), the exchange solution is stable, while the defect core solution becomes metastable. Comparing to the case with no initial disclination, the value at which the exchange solution becomes stable increases relatively. At a critical separation of d(c) ≈ 6ξ, the system undergoes a structural transition, and the defect core merges into a biaxial layer with large biaxiality. For weak anchoring boundary conditions, a similar structural transition takes place at a relative lower critical value. Because of the weakened frustration, the asymmetric boundary conditions repel the defect to the weak anchoring boundary and have a relatively lower critical value of d(a), where the shape of the defect deforms. Further, the response time between two very close cell gaps is about tens of microseconds, and the response becomes slower as the defect explodes. Molecular Diversity Preservation International (MDPI) 2013-12-12 /pmc/articles/PMC3876101/ /pubmed/24351807 http://dx.doi.org/10.3390/ijms141224135 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Zhou, Xuan
Zhang, Zhidong
Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title_full Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title_fullStr Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title_full_unstemmed Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title_short Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
title_sort dynamics of order reconstruction in a nanoconfined nematic liquid crystal with a topological defect
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3876101/
https://www.ncbi.nlm.nih.gov/pubmed/24351807
http://dx.doi.org/10.3390/ijms141224135
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AT zhangzhidong dynamicsoforderreconstructioninananoconfinednematicliquidcrystalwithatopologicaldefect