Cargando…
Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect
At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference i...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International (MDPI)
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3876101/ https://www.ncbi.nlm.nih.gov/pubmed/24351807 http://dx.doi.org/10.3390/ijms141224135 |
_version_ | 1782297469490561024 |
---|---|
author | Zhou, Xuan Zhang, Zhidong |
author_facet | Zhou, Xuan Zhang, Zhidong |
author_sort | Zhou, Xuan |
collection | PubMed |
description | At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference iterative method. Our results show that with the cell gap decreasing, the core of the defect explodes, and the biaxiality propagates inside the cell. At a critical value of d(c)* ≈ 9ξ (where ξ is the characteristic length for order-parameter changes), the exchange solution is stable, while the defect core solution becomes metastable. Comparing to the case with no initial disclination, the value at which the exchange solution becomes stable increases relatively. At a critical separation of d(c) ≈ 6ξ, the system undergoes a structural transition, and the defect core merges into a biaxial layer with large biaxiality. For weak anchoring boundary conditions, a similar structural transition takes place at a relative lower critical value. Because of the weakened frustration, the asymmetric boundary conditions repel the defect to the weak anchoring boundary and have a relatively lower critical value of d(a), where the shape of the defect deforms. Further, the response time between two very close cell gaps is about tens of microseconds, and the response becomes slower as the defect explodes. |
format | Online Article Text |
id | pubmed-3876101 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | Molecular Diversity Preservation International (MDPI) |
record_format | MEDLINE/PubMed |
spelling | pubmed-38761012013-12-31 Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect Zhou, Xuan Zhang, Zhidong Int J Mol Sci Article At the wall in a hybrid nematic cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Within the Landau-de Gennes theory, we have investigated the dynamics of s = ±1/2 wedge disclinations in such a cell, using the two-dimensional finite-difference iterative method. Our results show that with the cell gap decreasing, the core of the defect explodes, and the biaxiality propagates inside the cell. At a critical value of d(c)* ≈ 9ξ (where ξ is the characteristic length for order-parameter changes), the exchange solution is stable, while the defect core solution becomes metastable. Comparing to the case with no initial disclination, the value at which the exchange solution becomes stable increases relatively. At a critical separation of d(c) ≈ 6ξ, the system undergoes a structural transition, and the defect core merges into a biaxial layer with large biaxiality. For weak anchoring boundary conditions, a similar structural transition takes place at a relative lower critical value. Because of the weakened frustration, the asymmetric boundary conditions repel the defect to the weak anchoring boundary and have a relatively lower critical value of d(a), where the shape of the defect deforms. Further, the response time between two very close cell gaps is about tens of microseconds, and the response becomes slower as the defect explodes. Molecular Diversity Preservation International (MDPI) 2013-12-12 /pmc/articles/PMC3876101/ /pubmed/24351807 http://dx.doi.org/10.3390/ijms141224135 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Article Zhou, Xuan Zhang, Zhidong Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title | Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title_full | Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title_fullStr | Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title_full_unstemmed | Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title_short | Dynamics of Order Reconstruction in a Nanoconfined Nematic Liquid Crystal with a Topological Defect |
title_sort | dynamics of order reconstruction in a nanoconfined nematic liquid crystal with a topological defect |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3876101/ https://www.ncbi.nlm.nih.gov/pubmed/24351807 http://dx.doi.org/10.3390/ijms141224135 |
work_keys_str_mv | AT zhouxuan dynamicsoforderreconstructioninananoconfinednematicliquidcrystalwithatopologicaldefect AT zhangzhidong dynamicsoforderreconstructioninananoconfinednematicliquidcrystalwithatopologicaldefect |