RbH(2)AsO(4)

RbH(2)AsO(4), rubidium di­hydrogenarsenate (RDA), was synthesized by partial neutralization of an aqueous H(3)AsO(4) solution with aqueous Rb(2)CO(3). Its paraelectric room-temperature phase is composed of virtually regular tetra­hedral [AsO(2)(OH)(2)](−) anions and Rb(+) cations, both located on -4...

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Detalles Bibliográficos
Autor principal: Stöger, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884234/
https://www.ncbi.nlm.nih.gov/pubmed/24454010
http://dx.doi.org/10.1107/S1600536813026676
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author Stöger, Berthold
author_facet Stöger, Berthold
author_sort Stöger, Berthold
collection PubMed
description RbH(2)AsO(4), rubidium di­hydrogenarsenate (RDA), was synthesized by partial neutralization of an aqueous H(3)AsO(4) solution with aqueous Rb(2)CO(3). Its paraelectric room-temperature phase is composed of virtually regular tetra­hedral [AsO(2)(OH)(2)](−) anions and Rb(+) cations, both located on -4 positions. The [AsO(2)(OH)(2)] units are connected via O—H⋯O hydrogen bonds into a three-dimensional network, whereby the H atoms are equally disordered between the O atoms. The Rb(+) cations are located in channels running along the <100> directions and coordinated by eight O atoms located at the vertices of a snub disphenoid.
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spelling pubmed-38842342014-01-17 RbH(2)AsO(4) Stöger, Berthold Acta Crystallogr Sect E Struct Rep Online Inorganic Papers RbH(2)AsO(4), rubidium di­hydrogenarsenate (RDA), was synthesized by partial neutralization of an aqueous H(3)AsO(4) solution with aqueous Rb(2)CO(3). Its paraelectric room-temperature phase is composed of virtually regular tetra­hedral [AsO(2)(OH)(2)](−) anions and Rb(+) cations, both located on -4 positions. The [AsO(2)(OH)(2)] units are connected via O—H⋯O hydrogen bonds into a three-dimensional network, whereby the H atoms are equally disordered between the O atoms. The Rb(+) cations are located in channels running along the <100> directions and coordinated by eight O atoms located at the vertices of a snub disphenoid. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884234/ /pubmed/24454010 http://dx.doi.org/10.1107/S1600536813026676 Text en © Berthold Stöger 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Stöger, Berthold
RbH(2)AsO(4)
title RbH(2)AsO(4)
title_full RbH(2)AsO(4)
title_fullStr RbH(2)AsO(4)
title_full_unstemmed RbH(2)AsO(4)
title_short RbH(2)AsO(4)
title_sort rbh(2)aso(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884234/
https://www.ncbi.nlm.nih.gov/pubmed/24454010
http://dx.doi.org/10.1107/S1600536813026676
work_keys_str_mv AT stogerberthold rbh2aso4

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