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Bis(2-methoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
The asymmetric unit of the title compound, (C(8)H(12)NO)(2)[Mn(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, consists of half an Mn(II) complex anion, a 2-methoxybenylammonium cation and a solvent water molecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octah...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884241/ https://www.ncbi.nlm.nih.gov/pubmed/24454017 http://dx.doi.org/10.1107/S1600536813026366 |
Sumario: | The asymmetric unit of the title compound, (C(8)H(12)NO)(2)[Mn(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, consists of half an Mn(II) complex anion, a 2-methoxybenylammonium cation and a solvent water molecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octahedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water molecules. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). An intramolecular N—H⋯O hydrogen bond is also observed. |
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